Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(III) complex.

نویسندگان

  • Yukun Zhao
  • Junqi Lin
  • Yongdong Liu
  • Baochun Ma
  • Yong Ding
  • Mindong Chen
چکیده

A mononuclear Co complex, [Co(III)(DPK·OH)2]Cl (DPK = di(2-pyridyl)ketone), was synthesized and reported as a stable catalyst in visible light-driven water oxidation. The optimum turnover number (TON) of complex 1 is 1610, which, to the best of our knowledge, is the largest TON among metal-organic complexes for photocatalytic water oxidation.

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عنوان ژورنال:
  • Chemical communications

دوره 51 97  شماره 

صفحات  -

تاریخ انتشار 2015